Math skills for chemistry›Handling Data (M1)

Handling Data (M1)

Build confidence with significant figures, means, probability and uncertainty propagation for practical and exam questions.
4 min

Answers to calculations should be given to an appropriate number of significant figures.

For multiplication and division, give the answer to the same number of significant figures as the value with the fewest significant figures.

For example:

5.9 has the fewest significant figures (2), so the final answer should be given to 2 significant figures.

For addition and subtraction, give the answer to the same number of decimal places as the value with the fewest decimal places.

Add to favourites

Question walkthrough

Using an appropriate number of significant figures and rounding answers

,

In a multi-step calculation, keep intermediate values unrounded. Rounding too early can change the final answer.

For example:

but

Remember, round only the final answer.

Add to favourites

At the end of a calculation, you need to round an answer, usually to a number of significant figures.

An educational graphic explaining how to round the number 3.4495 to two significant figures, showing that it becomes 3.4. An arrow points to the text that states the importance of considering the third significant figure when rounding.
Do

When rounding to a number of significant figures, do only look at the next significant figure to the right.

An educational graphic explaining rounding numbers to two significant figures. It shows the number 3.4495 being rounded to 3.45, with annotations indicating which digits are not considered and noting that the original number has three significant figures.
Don't

Do not confuse decimal places and significant figures.

Do not round sequentially. For example, do not consider any digits beyond the third significant figure when rounding a number to two significant figures.

Add to favourites

Zeroes at the end of a value can be significant figures.

An educational graphic explaining that the number 6.99 rounds to 7.0 when expressed to two significant figures, emphasizing that the zero is a significant figure and not a placeholder.
Do

Remember to include zeroes at the end of a value where they are significant figures rather than placeholders.

Text explaining that 6.99 is not rounded to 7 when considering significant figures, as it only has one significant figure.
Don't

Forget to include zero where it is a significant figure at the end of a value.

Add to favourites

When taking measurements repeat readings are used to improve the reliability of the results. A mean () can then be calculated.

A diagram illustrating the formula for the arithmetic mean, represented as x̄ = Σx/n. Arrows point to explanations: 'Arithmetic mean', 'The total of all the values added together', and 'Number of values'.

Before calculating a mean, identify anomalous results (or outliers). These should only be excluded if there is a valid reason for doing so.

Add to favourites

Question walkthrough

Calculating arithmetic means

Determine the arithmetic mean of three measurements recorded by a student.

When you have taken multiple measurements, one or more may be outliers.

There are no absolute rules for dealing with these results, and you need to consider each case.

Ask yourself:

  • Was the suspected anomaly recorded in error?
  • Was the suspected anomaly recorded in different conditions from the other values?

If you answer yes to either of these questions, then you can consider the value as anomalous and omit it from the dataset. You should calculate the mean using the remaining values.

For example, a student repeatedly drops effervescent tablets into fresh cups of hot water and measures the time it takes for the reaction to complete.

A table displaying measurements and corresponding time in seconds. The first column lists measurement numbers from 1 to 7, while the second column shows their respective times: 25.3, 25.6, 32.1 (crossed out), 24.9, 19.8 (crossed out), 25.5, and 25.6 seconds.
Do

Consider the questions carefully. You will need to justify why you consider the reading to be anomalous.

If you spot a potentially anomalous reading while you are carrying out the experiment, repeat the reading.

A table displaying measurements and corresponding time in seconds. The first column lists measurement numbers from 1 to 7, while the second column shows times ranging from 24.3 seconds to 26.3 seconds, with some values crossed out.
Don't

Just exclude a value because there is a larger difference between it and the other values.

You need to have good reasons for thinking that a value is anomalous.

Add to favourites

Question walkthrough

Calculating weighted means

,

When you take a measurement, there is an uncertainty because no measuring instrument can show unlimited precision.

The precision offered by the instrument is called its resolution. This is usually determined by the scale on the instrument and is half of the smallest division on the scale.

Absolute uncertainty is the amount by which a measurement could differ from the actual value.

,

The smallest division on the scale above is

The absolute uncertainty is half of the smallest division.

So the uncertainty in the temperature is

Add to favourites

You can calculate the relative uncertainty or percentage uncertainty using the equation:

The percentage uncertainty indicates the absolute uncertainty relative to the measured quantity.

,

The smallest unit on the balance scale is So, the absolute uncertainty in the measurement is

It is useful to know that when measured quantities are smaller, the percentage uncertainty is greater. An example of this is when a balance is used to measure a mass of the percentage uncertainty will be much greater than a mass of

This is because the number you are dividing the absolute uncertainty by is much smaller.

Add to favourites

Question walkthrough

Calculate relative uncertainty in a measurement

Doubles the thermometer’s reading uncertainty to account for two readings (initial and final), then finds the percentage uncertainty in a recorded temperature change.

Always add the absolute uncertainties in the measurements when calculating the percentage uncertainty in the difference between two measurements.

For example, a student records two temperatures, and using a thermometer marked in divisions.

They calculate the percentage uncertainty in the temperature difference.

Do

Sum the absolute uncertainties.

Don't

Subtract one absolute uncertainty from the other absolute uncertainty.

Add to favourites

Question walkthrough

Calculate relative uncertainty when two measurements are added or subtracted

Doubles the thermometer’s reading uncertainty to account for two readings, then finds the percentage uncertainty in the temperature difference between two measurements.