Math skills for chemistryHandling Data (M1)

Handling Data (M1)

Build confidence with significant figures, means, probability and uncertainty propagation for practical and exam questions.
4 min

You need to be able to give answers to calculations using a number of significant figures that is appropriate for the number of significant figures in the values used.

You also need to be able to round the answer correctly. For example, look at this calculation:

Each value has a different number of significant figures. You can only give an answer to the same number of significant figures as the lowest number of significant figures in any of the values.

The value 5.9 has 2 significant figures, so the final answer should be given to 2 significant figures.

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Question walkthrough

Using an appropriate number of significant figures and rounding answers

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In a multi-step calculation, you must use the unrounded answer from one calculation in another.

If you use a rounded answer in the next calculation, the final answer may be different.

For example, if you rounded the first part of the calculation:

to two significant figures (9.212 rounds to 9.2), the final answer would be 8.3 instead of 8.4.

When using a scientific calculator:

A scientific calculator displaying a calculation result. The screen shows '2.8 x 3.29 ÷ 1.01 =' followed by the result '8.366391462306993' and a long number '64214350930724'. The calculator has various buttons including SHIFT, ALPHA, MODE, and SETUP.
Do

Keep the unrounded answer to all intermediate steps in the calculator’s memory.

A scientific calculator displaying the number 8.3 on its screen. The calculator features various buttons for mathematical functions, including shift, alpha, mode, and setup options, as well as buttons for trigonometric and logarithmic calculations.
Don't

Round the answers to intermediate steps to the number of significant figures needed for the answer.

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At the end of a calculation, you need to round an answer, usually to a number of significant figures.

An educational graphic explaining how to round the number 3.4495 to two significant figures, showing that it becomes 3.4. An arrow points to the text that states the importance of considering the third significant figure when rounding.
Do

When rounding to a number of significant figures, do only look at the next significant figure to the right.

An educational graphic explaining rounding numbers to two significant figures. It shows the number 3.4495 being rounded to 3.45, with annotations indicating which digits are not considered and noting that the original number has three significant figures.
Don't

Do not confuse decimal places and significant figures.

Do not round sequentially. For example, do not consider any digits beyond the third significant figure when rounding a number to two significant figures.

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Zeroes at the end of a value can be significant figures.

An educational graphic explaining that the number 6.99 rounds to 7.0 when expressed to two significant figures, emphasizing that the zero is a significant figure and not a placeholder.
Do

Remember to include zeroes at the end of a value where they are significant figures rather than placeholders.

Text explaining that 6.99 is not rounded to 7 when considering significant figures, as it only has one significant figure.
Don't

Forget to include zero where it is a significant figure at the end of a value.

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When taking measurements in science, you usually take at least three readings.
The average value of the readings, or the arithmetic mean, is calculated and used in subsequent calculations.

Calculate the mean ( ) using:

A diagram illustrating the formula for the arithmetic mean, represented as x̄ = Σx/n. Arrows point to explanations: 'Arithmetic mean', 'The total of all the values added together', and 'Number of values'.

Sometimes you obtain readings that are anomalous (or outliers), and you need to consider what to include or exclude them.

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Question walkthrough

Calculating arithmetic means

Determine the arithmetic mean of three measurements recorded by a student.

When you have taken at least three readings of a measurement, one reading may be anomalous or an outlier.

There are no absolute rules for dealing with these results, and you need to consider each case.

Ask yourself:

  • Was the suspected anomaly recorded in error?
  • Was the suspected anomaly recorded in different conditions from the other values?

If you answer yes to either of these questions, then you can consider the value as anomalous and omit it from the dataset. You should calculate the mean using the other values.

For example, a student repeatedly drops effervescent tablets into fresh cups of hot water and measures the time it takes for the reaction to complete.

A table displaying measurements and corresponding time in seconds. The first column lists measurement numbers from 1 to 7, while the second column shows their respective times: 25.3, 25.6, 32.1 (crossed out), 24.9, 19.8 (crossed out), 25.5, and 25.6 seconds.
Do

Consider the questions carefully. You will need to justify why you consider the reading to be anomalous.

If you spot a potentially anomalous reading while you are carrying out the experiment, repeat the reading.

A table displaying measurements and corresponding time in seconds. The first column lists measurement numbers from 1 to 7, while the second column shows times ranging from 24.3 seconds to 26.3 seconds, with some values crossed out.
Don't

Just exclude a value because there is a larger difference between it and the other values.

You need to have good reasons for thinking that a value is anomalous.

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Question walkthrough

Calculating weighted means

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When you take a measurement, there is an uncertainty because no measuring instrument can show unlimited precision.

The precision offered by the instrument is called its resolution. This is usually determined by the scale on the instrument and is half of the smallest division on the scale.

Absolute uncertainty is the amount by which a measurement could differ from the actual value.

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The smallest division on the scale above is

The absolute uncertainty is half of the smallest division.

So the uncertainty in the temperature is

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You can calculate the relative uncertainty or percentage uncertainty using the equation:

The percentage uncertainty indicates the absolute uncertainty relative to the measured quantity.

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The smallest unit on the balance scale is So, the absolute uncertainty in the measurement is

It is useful to know that when measured quantities are smaller, the percentage uncertainty is greater. An example of this is when a balance is used to measure a mass of the percentage uncertainty will be much greater than a mass of

This is because the number you are dividing the absolute uncertainty by is much smaller.

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Question walkthrough

Calculate relative uncertainty in a measurement

Doubles the thermometer’s reading uncertainty to account for two readings (initial and final), then finds the percentage uncertainty in a recorded temperature change.

Always add the absolute uncertainties in the measurements when calculating the percentage uncertainty in the difference between two measurements.

For example, a student records two temperatures, and using a thermometer marked in divisions.

They calculate the percentage uncertainty in the temperature difference.

Do

Sum the absolute uncertainties.

Don't

Subtract one absolute uncertainty from the other absolute uncertainty.

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Question walkthrough

Calculate relative uncertainty when two measurements are added or subtracted

Doubles the thermometer’s reading uncertainty to account for two readings, then finds the percentage uncertainty in the temperature difference between two measurements.